Last Modified December 24th  2006

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Sammy Sambu and Richard Wilson
Chronic Arsenic Poisoning:
History, Study and Remediation

 
Introduction
Countries
Books
Conferences
References
Measurement
Site History
REMEDIATION
Links
  Harvard/MIT Faculty
Searchable Address List
(not now available)
Online Articles
Chronic Health Effects
Pictures of Sufferers
Prof Wilson's Page


Final report of Deep aquifer Data BAse and Preliminary Deep Aquifer Map.  (Local Government Division,  GoB March 2006)

A tubewell such as that shown above is simple to drill and seems to get pure water.  BUT  one quarter of the wells drilled in Bangladesh tap an aquifer containing too much arsenic. An overview of the arsenic problem in  Bangladesh written by the webmaster can be found here.

Will you Help?

Various Charitable organizations are helping to bring pure water to Bangladesh and SE Asia.   This webmaster suggests  that you financially support one or all (any currency and airline frquent flyer coupons gratefully accepted:

The ARSENIC FOUNDATION INC.
(or direct link http://arsenicfoundation.com)
PROJECT WELL
OTHERS?

Providing Pure Water

    It is important to distinguish the problems in most of the world, where high arsenic levels are rare, from the problems in Bangladesh and Bengal.   In most of the world, once arsenic has been discovered in drinking water,  the most important action is to provide pure water to those who have been  drinking from the wells.  This was the action taken, for example, in Taiwan, in Chile, and in Inner Mongolia (as soon as the problem was understood).    In the developed countries (in which we include Chile and Taiwan) provision  of pure water is simple, and not overly expensive.  In the United States of America, only a few water supplies hae levels of arsenic above 50 ppb, and even the number with levels above the standard of 10 ppb should be easily manageable.   In our listing of remediation technologies we must distinguish methods appropriate for the U.S.A. (and large cities) and those appropriate for villages in Bangladesh West Bengal and Southeast Asia generally.    We concentrate on the latter.

    For Bangladesh there is now a NATIONAL WATER POLICY.     There are various annexes with instructions on how to fulfil various parts of the policy.  The various file are listed in this directory.  Professor Dipankar Chakraborti who has worked for 18 years on these problems recently (2005) outlined his strategies for mitigation of the arsenic problems in West Bengal and Bangladesh.    It may be downloaded in full but this webmaster will quote from various parts of it in due course. In the opinion of this webmaster there is no conflict between these various options for getting pure water.     

    This webmaster believes, first and foremost, that it is important to make the villagers fully aware of the problem and involve them in the solution.   It is vital to gain their confidence.   In this connection it is important that, according to a recent study,  villagers seem to be more willing to pay for running water than for arsenic free water.    Thus, any solution which leads toward running water is to be preferred (see the second and third phases of the DCH program on dugwells below).   It is important to listen to women in the villages as well as to men.  Women do most of the water carrying.

    At the WHO conference and at the 5th International Arsenic Conference in San Diego in July 2002 several different  methods were discussed as appropriate for different places.    The Bangladesh Arsenic Mitigation Water Supply Project recommended the first three of these. 
    See also a thoughtful description of the alternatives is by Professor Feroze Ahmed of Bangladesh University of Engineering Technology (BUET), in a paper presented at that conference in Dhaka,   and  Professor Ahmed's  edited volume of various recommendations on the problem that is available from ITN, BUET in Bangaldesh.   In all cases it is important to discuss these in the context of the geology of the country, and region concerned.  See the report for the Government of Bangladesh Quaternary Geology and Aquifer Systems in the Ganges-Brahmaputra-Meghna Delta Complex, Bangladesh  

    
The number of people supplied by each system  varies and the total number of Bangaldeshis is therefore not certain.  It is probably less than 10% of the number of  Bangladeshis who need pure water.   This depends upon the nature of the supply systems.  It would be useful if there was a continuous monitoring of the number of systems needed.    This webmaster believes that in all cases it is necessary to monitor the solution Is it indeed providing arsenic free water,  bacteria free water a year later?  Measurement is therefore an essential part of any remediation method.   

Small Scale Arsenic Removal  Methods


         

    The KANCHAN filter as used in Nepal

    At the first  International Conference  on Arsenic in drinking water, held in Dhaka in February 1998 simple methods for each household to filter the water were suggested as an immediate short term solution. 
They have in common a series of containers.  Water is poured into  the top container and filters  through sand and iron chips to the bottom container where the water is now free  of arsenic.  It was hoped that these methods would be easily used by villagers,  would use local materials,  and be affordable.    Several groups  claim lasting success.  

   
Guy Howard of the Bangladesh Arsenic Policy Support Unit pointed out that there were, in August 2005,  100,000 household arsenic removal units in Bangladesh.   Dr Abul Hussam of George Mason University, with his brothers in Kushtia and Dhaka,  designed and market the  SONO/MSUK filter. 21,000 SONO filters have been distributed throughout Bangladesh by May 2006.   They are marketed from their base in Kushtia.  400,000 people drink water from these filters from may parts of Bangladesh as shown in the map..   PDF files of photographs and other details of the SONO filter can be downloaded.   Professor Abul Barkat of the University of Dhaka comments that they "have collected  data for last four years (that's how long some of these filters are running).   More than a billion liters of water has been consumed from these filters. The  filter has been optimized to last for seven years minimum at a cost of $35.00"     The system is continuously being modified and updated.   The importance of the back up that is provided for the SONO filter is the example of a dozen filters that were supplied in the village of Eurian in eastern Bangladesh where Dr Chakriborti of Kolkata and DCH are working.   The tests, in 2005,  of these filters in the field by DCH were far from satisfactory.   Dr Hussam believes this was due to a mnufacturing defect that has now been corrected and the group has relaced the filters at no charge.   The test results of the replacement  filters are excellent.  This emphasizes the importance for this method, of  expert back up. The need for expert back up  probably applies  for all mitigation methods!   A recent independent report on the SONO filter shows that this filter is playing a major role in reducing the Bangaldesh arsenic problem. Additional data on the tests on the SONO filter installed by BAMWSP-DPHE in Hagijang, Chandpurhas can be found here. Furthermore, the water quality test report on the SONO filter installed by the BAMWSP-DPHE in Gojaria, Munishijang  can be found here.

Dr. Susan Murcott of MIT    has been  developing a cheap and simple system, the KANSHAN filter for use in Nepal.   
Columbia University also report sucessful use of such devices, but when arsenic free water supplies were available, villagers preferred to get the arsenic free water. 

   
In other locations problems arose.   According to the 6th report by the Jadavpur University team, 80% of Arsenic Removal Systems (ARS) in West Bengal are not functional.  Not only is it a waste of several millions of dollars but also it is a tragedy of false hopes.        A possible reason for the failures is explained in this note from Professor McArthur.  "Do they know the water is Fe-rich? If not, find a way to tell them. It might change their view of the matter, because, unless Fe is removed before the As plant, it messes up a good deal of the removal technology currently available: and, as an Fe-removal plant aerates and precipitates FeOOH, it removes most of the As. This is standard (old) technology. If they fund someone who does not know the water is Fe-rich (and most don't) they may put a big sum into methods doomed to fail. Attached is a good example: a year old and doomed to follow 20 or so other clones now abandonded that litter my field area in West Bengal. Raw feed is 900, output 300 and climbing, blocked by Fe most of the time: a disaster."   

    It seems clear that the reliability and effectiveness of Arsenic Removal Systems depends upon the water chemistry, and probably on the maintenance.   It is also unclear whether laboratory experience is predictive of performance in the field.  It is unclear to this webmaster whether there exist ARS that work on all waters in Bangladesh and which they are;  and if a particular ARS only works on some waters how to decide whether it will work on a particular village water and how to explain all of this to the villagers affected.

  
Although the situation is far from clear,   Dr S-Amiri of OCETA has a small report discussing both iron and phosphate as possible system cloggers.    recent addition to the list of on line articles discusses a simple stainless steel filter.  The following interchange where the STATESMAN exagerrated the implications of a suggestion that the iron/arsenic interaction might be reversed, illustrates the problem. It is important NOT to blindly install devices which have not been tested.

   
  In 1978 the Government Of Bangladesh   instituted a program called ETV-AM (Environment Technology Verification-Arsenic Mitigation) to verify the claims regarding the efficacy of Arsenic Removal Technologies and  appointed BCSIR ( Bangladesh Council of Scientific and Industrial Research) to carry out this program. BCSIR is being assisted by OCETA (Ontario Center for Environmental Technology Advancement) of Canada. This program is supported by CIDA and BAMWSP (Bangladesh Arsenic Mitigation Water Supply Project financed by the World Bank).      Under the current GOB regulations, no arsenic removal technology may be deployed in Bangladesh unless it is cleared by the ETV-AM program.    In February 2004 four technologies were approved for "provisional" use and are now being sold -READ-F, SONO 45-25 (the system noted above designed by Dr Hussam), Sidko and MAGC/ALCAN.   Unfortunately only scanty details are available in a poster and a pdf file of some tables, so that this webmaster is unclear under what conditions OCETA claim they will work.  Dr  Hussam of SONO claims that some of the data in that poster are meaningless. Nor has this webmaster been able to find an independent expert who understands enough to inform him.   Therefore this webmaster awaits the complete report.   It was ora;;y stated at the American Chemical Society meeting in March 2006, that the report has just been released.  But as of mid-May 2006 the webmaster has been unable to get a copy.      Perhaps the Grainger Challenge Prize will stimulate both a well designed system and  full,  publicly available, well documented,   systems.     The webmaster was also promised, January 2006,  details of the SIDKO and MAGC/ALCAN systems which will be posted as soon as available.    

    The pessimistic concusions of Chakriborti and McArthur are also challenged in West Bengal by Arup Sengupta of Lehigh University and his colleagues in Bengal Engineering College.   Their detailed paper of the results of followup on over 150 medium sized systems seems convincing.      The cost is about $1,200 for a unit which purifies water for 300 families or about 1200 people.  This works out at $1 per person.   Anyone interested should call Dr Anriban Gupta at Bengal College.   In Bangladesh,


    This webmaster makes a  tentative conclusion:  it is vital to have a village community that is committed to follow up maintenance and hopefully a nearby institution  for expert backup information and advice.
ector, School of Environmental Studies, Jadavpur University”. 
Well switching


Left. a well painted green(water safe) and, right, one marked red(arsenic content  is toxic).

    It is important to understand the causes of the availability of arsenic in the tube wells and the extent to which the problems can be avoided by careful choice of wells.   John McArthur of University College, London, emphasizes that 75% of the shallow wells are doing what was intended - providing pure water.    The general view is that 33% of the people in Bangladesh villages have switched wells in respone to the general advertiseent of the problem.  The team of Columbia University and University of Dhaka scientists find that in Ariahazar upazilla, where they have been working, 68% of people have switched wells.  This well switching is the cause of the biggest number of persons now drinking arsenic free water who were not before.  Yet in a Government of Bangaldesh survey, this still leaves 1400 villages without any well that is free of arsenic.  Obviously, these villages are priority villages for the pilot projects for the various technologies discussed below.  

    There are two thoughts that may enable continued use of tube wells.   John McArthur has reinterpreted the data of Harvey et al. to suggest that continuous pumpling (especially for irrigation) is flushing (removing) the arsenic from the shallow aquifer in many places.  This optimistic, highly speculative, but  but exciting thought is discussed in his paper
in press.   Another long shot arises from the belief that the arsenic is liberated when iron oxides are reduced in the anoxic ground layers just beelow the survface, liberating the attached arsenic.   This suggestes to Professor Harvey and others that the aquifer might be purified by inserting oxidizing agents.  A small trial with some nitrates reduced the arsenic levels for a week, and a more massive trial will gtake place in January 2006.

    A report by APSU (November 2004) entitled
"not just  red or green?" discusses this issue in a very clear way and makes several important recommendations.



    Use of Deep Wells

   The information from  well water surveys such as that of the British Geological Survey and Mott MacDonald   shows that deep wells, greater than 150 meters in depth, are free of arsenic.   This seems to be confirmed by more detailed studies from an MIT/BUET (and others) group and a Columbia University group.   Dhaka and the southern part of Bangladesh (where salt water enters the shallow aquifer)  are mostly free of arsenic.  But this may not be true everywhere.   Although about twice the price of a shallow well,  deep  wells  could be used and are cheaper ($100) than most other alternatives.   ($200 for a renovated and $300 for a new dug well) For a village based unit this comes to around $1 per person.  Dr Colin Davis of UNICEF was recommending their use at the 5th International Arsenic Conference in San Diego in July 2002, and the Columbia University scientists are recommending them as the cornerstone of a major program.    It was reported  in the New Nation on December 28th 2004  that the World Bank is spending $44 million to install deep tubewells in appropriate arsenic contaminated areas.  

    Since it it is one of the cheapest methods, it is hard not to support the idea.   Although the 1992 WHO conference and BAMWP only conditionally recommend them, BAMWP has provided 300 deep tube wells in coastal areas.   It is reported that the World Bank is financing many such wells.  But there are potential  problems that should be considerd in any implementation:
    - if such wells are dug carelessly, and not properly grouted, there is a possibility of "shunting" the aquifers and allowing water from the higher aquifer to contaminate the lower aquifer. 
    - it is unsure whether the lower acquirer is a "closed" acquifer from a hydrogeologic point of view or whether it is as easily recharged as the upper aquifer.  
    - It is unclear whether, in a longer term, pumping from these wells would increase the arsenic level.

    However, these can be checked by frequent (once a year) measure of the arsenic levels.  If arsenic levels are rising,  other solutions must immediately be found.   Since money would be saved by using this cheaper method,  the money could be set aside for such eventualities in what, we all hope, would be a limited number of locations.  Without such a committment in advance, the webmaster is dubious about using deep tubewells as a panacea.   They are, however, one of a set of possible solutions, available in appropriate places with appropriate precautions.   We have attached some opinions of experts in 2002 and of Dr Dipankar Chakraborti in 2005.    The Phase 1 report of June 2004 by the Arsenic Policy Support Unit (APSU) "Risk Assessment of Arsenic Mitigation Options (RAAMO)" finds little arsenic and almost no bacteria in a selected group of deep tube wells.   Nominally they were selected randomly but that means little since it is strongly believed that the quality of deep wells is very dependent on geography.   Nonetheless this is highly encouraging and suggests that some of the caution in the use of deep tube wells may not be justified.   Indeed this reviewer would emphasize that at the worst, a deep tubewell would produce arsenic-free water for 10-20 years, and might do so for well over 100 years.   Since the cost is lower than other alternates, t it would in most cases be well worth a try.
 
    See also the Bangladesh government reports:-  Ground Water Task Force, July, 2002  Full Final report of Deep aquifer Data base and Preliminary Deep Aquifer Map.  (Local Government Division,  GoB March 2006)  ContentsChapters1&2  ,  Chapter3Chapter4  ,  Chapter5.1-5.4
Chapter5.4-5.44 Chapter5.5 , Chapter 6 Chapter7Con  , Chapter8Ref Chapter9Appendices
                                                                        

      Return to Surface waters.

    It seems to be the official Bangladesh National Water Policy to return to the use of surface waters whenever possible, in spite of the fact that many communities have excellent water supplies from groound water (deep wells).   In the directory there is included the
Report of  the Committee on Surface Water Development and Management for Drinking Water Supply in the Arsenic affected areas of Bangladesh, July 2003  .  In the viwe of this webmaster this report pays inadequate attention to assuring sanitation.    An excellent papr describing how approaches to sanitation have changed in the last 150 years is by Okun.

     In the past (50 years ago) many of the villagers drank from "holy" ponds where the water was protected from animals and cattle. Many of these were unsanitary. It was to prevent water borne diarrheal diseases that the tube wells were suggested.
   A return to surface waters must therefore be done with full regard to better sanitation than before.  In particular this webmaster recommends rigid adherence to WHO standards.    Waters should be tested for coliform bacteria, not just once but regularly and in particular at the worst period - the end of the dry season.   
Disinfectants , lime or chloride should be used regularly - every 3 months or whenever trouble is suspected.     Indeed in the USA Some wells are chlorinated daily.  Tests should be made before the disinfection, not only just afterwards,  to be representatative of the worst time.     Also in the rainy season when the ground is water logged and the ability to filter bacteria is lost.    Public confidence was lost when water from the tube wells were found to contain arsenic.  It was lost again when the Arsenic Removal Systems were not successful in many places.    Confidence once lost is hard to regain.   For that reason, among others, this webmaster recommends that in order to inspire public confidence these measurements must be available for public inspection  (for example the measurements of the dugwells installed by DCH are in a directory on this website.)  As of May 2006 this webmaster knows of no completely satisfactory protocl for coliform avoidance and testing in Bangladesh.   The successes and failures are discussed further below.    Tests must be made for coliform bacteria  frequently - how frequently is a matter still under discussion.    Unfortunately it is not yet clear that any of the organizations installing surface water systems are yet completely satisfactory.  This is discussed further below when the individual systems are discussed.

    Eventually each technology should be subjected to a risk assessment - comparing risks and benefits of the various options.   Even in developed countries such risk assessments are rare and can be misunderstood.   Since the major risk is not of death, a measure must be found of sickness.  two measures are in use for this "Quality Adjusted Life Years " lost (QALYs) and "Disability Adjusted Life Years" lost (DALYs).  See for example page 12 of "Risk Benefit Analysis"  A fine paper using such a procedure has been presented APSU, 
"Risk Assessment of Arsenic Mitigation Options (RAAMO)".    Not surprizingly,the Phase 1 (June 2004) report finds that the risks of improper use of surface waters outweighs the risk of badly installed deep tube wells.    But the data on the wells and ponds  surveyed is still is in its infancy (see below under individual systems) so that the webmaster warns against simplistic use of the numbers so far available.   

Use of Dug Wells

    Before the (cheap and simple) tube well was introduced,  many villages dug wells to obtain surface water.  However,   many, if not most,   were NOT carefully installed, dug, covered, and chemically treated, and they were full of bacteria.    Sucessful projects involving sanitary dugwells exist in other countries, and some that may be successful have been reported but not yet in the detail to convince the skeptics that no coliform bacteria exist.  

    Large Dug wells

Dr Chakraborti discusses dugwells in his 2005 list of mitigation stategies.  He has a large dugwell/pond system  in his ASHRAM which he descibes:  
  
"It is almost 3 years my model village people are drinking dug-well water. In my opinion my dug-well water is nectar,  complete balanced cations and anions, arsenic 8-18 microgram/l and iron ~100 microgram/l. Please find herewith the photograph of my dugwell. I have two ponds near my dugwell with two cement storage tanks 20 ft X 20 ft X 5 ft. The tank is two storied. Between upper and lower tank people can rest in summer,   as it is cold. Note my dugwell is 12 ft diameter with depth ~ 50 ft. It is a complete concrete structure. After two years of laboratory testing villagers are now allowed to drink the dug well water. To keep dugwell safe from bacterial contamination normally I make through cleaning twice a year and removing the sand and treating with KMNO4/bleaching powder  and NaOCl. Almost 2-3 days I do not use the dugwell (but stored water in tank serves the need). Most important fact even after cleaning  everyday at night I put 2 drops of NaOCl per 5 liters of water. I know the water level and a simple calculation will deecide how much NaOCl to be added.  If you do it regularly bacteria contamination is not there. From my dugwell 800 people can drink water.  Here are pictures"

Dr Chakraborti reports on tests of 483 dugwells in West Bengal confirming that most are arsenic free.   No measurements of coliform bacteria are available to this webmaster, but Dr Chakriborti recommended disinfection with chlorine once a month.

Project Well  in West Bengal, directed by Dr Meera Smith,  has published details on about 40 sanitary dugwells in West Bengal;  again the detailed lsiting on the coliform measurements and the timeing thereof is not avalaible to this webmaster.


   
Smaller Dugwells


    Initially both BRAC and the Grameen Bank installed many wells that did not follow WHO guidelines - some were uncovered for example.   But they  claim to have been been installing  dug wells with filtration.    However, the webmasters have no up to date report on their sucesses, failures, and costs in spite of diligent enquiry.   WE INVITE AND SOLICIT ANY AND ALL SUCH INFORMATION.  All we have are oral reports that 250 have been abandoned as being unsanitary - presumably because sanitary procedures (see below) have not been followed. 

    The  Arsenic Policy Support Unit (APSU), a Bangladesh Government group, reported in June 2004, and final a year later,  that 1,524 dugwells  had been dug by 6 groups:  BAMWSP, DPHE-Unicef, DPHE-Danida, World Vision, WATSAN, and Asia Arsenic Network.   They studied 351 wells in 6 clusters  "chosen at random."     T  "Risk Assessment of Arsenic Mitigation Options (RAAMO)",  on the bacteriological contamination is not encouraging - showing that 94% have bacterial contamination .    Although arsenic levels were low in most dugwells, a few had levels up to 100ppb.   As far as can be discovered from the RAAMO report APSU measured some wells paid for by UNICEF but never measured wells those paid for by UNICEF but dug by DCH.  They missed for example, any wells dug by Dhaka Community Hospital although their results were ncorrectly claimed to be representative of DCH wells (in Siridjikan in Table 3.2 of the June 2004 RAAMO report.  Although they claim to be a representaive sample, that claim, therefore is not substantiated,  Nor is it clear whether the claim to be  random has a useful meaning,  RAAMO have not put their detailed numbers on the web, and have made no comment on the measurements of the 48 wells dug by DCH for UNICEF that have been available on this site for over two years.   They seem to consider all dugwells as equal, although some follow WHO guidelines and some do not.  This is not appropriate    It seems that many, if not most, of the wells were badly sited, were not constructed using WHO guidelines, or did not use disinfectant (lime). 

    But that does not mean that the wells not discussed in RAAMO are all satisfactory.  Dhaka Community Hospital (DCH),   has supervised the installation of several hundred dugwells.   Three phases of a "pilot" project of 66 dugwells in the PABNA area in which the webmaster was proud to have assisted are reported here.   (2nd phase (in html) and  (msword); third phase in MSWORD) A detailed paper has been submitted to  a journal.    Initial measurements showed that they were free of arsenic and bacteria  as   shown here in EXCELBut later masurements showed high levels of colifor bacteria.  The capital cost for arsenic free water in the kitchen works out at less than $70 per family or $5 per person. This webmaster  cannot resist showing pictures from his visit (in February 2004) to several villages in the PABNA area.    Starting in the second phase (2003) water is pumped to a small storage tank from which there is piping to individual houses.  (also msword file)  (layout of the piping).    Measurement of 48  wells supervised by DCH in 2003-2004 for UNICEF in Sirajdikhan Upazila also showed few  bacteria (and little arsenic) in the initial testing,;  moreover some of these measurements were confirmed by independent testing by IDDRB.  But later masurements of some of the PABNA wells showed high levels of coliform bacteria.   The webmaster speculatesat the initial tests were made just after chemical treatement with lime, and the bacteria increased thereafter.  Another suggestion, made in .another report on the APSU website,  is that the PABNA wells themselves were cracked so that during the rainy period water went staright into the well from the surface without filtration.   Studies are being undertaken to study this so that  public confidence can be restored.  It may well turn out that the cost of maintaining bacteria free wells is too large for a small well with few users.   This obviously puts additional emphasis on pipeline systems where more people can be served from a single, somewhat larger, dugwell.   Meanwhile wells are being chlorinated every 3 months.
 

     As noted above some early attempts to provide pure water did NOT pay attention to sanitary procedures.    In the past many wells were too close to latrines and animals were not kept away. A modern dug well (following WHO has suggested guidelines for modern dugwells.  They must be covered to prevent entry of animals and refuse but is aerated to allow oxidization.  Water is taken out by a connected tube well and pump, making them as easy to use as a tube well. They are located at a distance from latrines including past latrines with their buried organic waste if possible.  DCH  and Chakriborti ave developed written instructions for correct intallation.     Grameen Bank now has a similar list. The wells  must of course be tested for arsenic, manganese and other heavy metals,  initially and perhaps every 2 years.    But tests must be made for coliform bacteria more frequently - how frequently is a matter still under discussion.  Dr Khaliquzzaman of the World Bank also has a short report on dugwell test and maintenance with similar warnings to those in the DCH report noted above. Reports on dugwells are listed in this   directory including many more pictures of dugwells in Bangladesh

    The dugwells, with pipeline,  are a further step in matching the history of the water supply in the small English village in which Richard Wilson lived from 1953-1955.  For several centuries, a village well existed from which everyone drew water in a bucket.  In the 1930s, the well was covered and a windmill installed to pump water to a storage tank with water supply to one tap in each cottage.  The cottages were "modernized" by installing staicases to the upper floors to replace the ladder.  In the 1940s a small petrol (gasoline) engine supplemented the windmill when the wind died down, and a bathroom was installed in the cottage in which Richard Wilson lived.  In the 1960s, the main water supply pipe to the city of Oxford was brought within 1/2 mile and the village connected to main water.   

    In 1998 it was a puzzle to many geologists,  and even some hydrogeologists,  why the surface wells were free of arsenic. For they seemed to be sample the same water as the shallower tube wells, and in many locations shallow tube wells showed concentrations of arsenic concentrations increaing with time.   Why does this not happen in dugwells?   This question, asked 6 years ago has never been satisfactorily answered.   There are several possible answers.  Firstly, over centuries people used dugwells, mostly unsanitary, but no arsenic problems were ever reported.  Secondly the experience of DCH, Meera Smith and Dipenkar Chakraborti suggest a difference.   
They claim that the shallow dug wells were likely to be less polluted than shallow tube wells because, being wider (often over a meter diameter) they allowed access of oxygen and so would oxidize dissolved ferrous iron and that would scavenge arsenic from the water.  Also the top of the aquifer is the freshest, youngest water,   which has been most recently recharged by flood (rain) water,    and so the least likely to be polluted by iron reduction.   On coming to the surface in a dug well the water oxidizes and deposits arsenic,  by co-precipitation with FeOOH or sorption onto existing FeOOH in the sediment.    This argument may not apply to a small dugwell where water is continually coming in from the side and aeration may not be complete.     

    The dug wells generally sample water that is shallower than the shallow tube wells. Dug wells are dug until the water table is hit, plus a bit more. Those dug in December, when the water table is high,  sometimes went dry in a dry year.  They were often a bit shallower than those dug in May at the end of dry season.  Shallow tube wells are sunk until the first good clean aquifer sand in found, then are made 20 foot deeper to accommodate the screen,   Much of the pipe comes in 20 feet lengths, so that "shallow" tube wells may be 20 to 30 meters deep (5-7 pipe lengths, including screen).

 Rainwater Harvesting
    


 

Household tanks with a capacity of 3200 litres. Photo courtesy of UNICEF-Bangladesh.

     Rainwater harvesting is estensively practiced in India (W Bengal). Attached is a comment by Dr Meera Smith.

    For anyone unfamiliar with the cycle of monsoon rain and long dry season, it is puzzling why there is a problem  in Bangladesh at all.  One of the web masters lived in an English village where rain water harvesting and storage was usual. But storage was only needed for several weeks.   In Bangladesh water must be stored for several (none!) months.   The size of the tank must be increased tenfold,  and it becomes difficult, although vitally important, to keep the water pure during storage.  Nonetheless it is a solution for many communities where other alternates are not available.  Particularly in southern Bangladesh, where there is frequent flooding, it is almost impossible to make a sanitary surface well, because it is not possible to keep the latrines at a distance from the wells.   Rainwater harvesting is being advocated by UNICEF as reported by Dr Colin Davis at the 5th International Arsenic Conference in San Diego in July 2002.
   As of February 2004,   1000 new rainwater harvesting units were being installed by UNICEF and DCH

    Simple storage of rainwater is not as simple a solution as it may appear from the above description. In some high-iron waters little or no arsenic is found.  Everyone who has looked for microbiological contamination of such stored waters has found gross contamination - water containers act as incubators in the house, especially when they are uncovered or do not have taps. After 12 hours, fecal coliforms can be more than 10,000/100ml, or even 'TNTC' (too numerous to count).       
The Phase 2 report of May 2005 by the Arsenic Policy Support Unit (APSU) "Risk Assessment of Arsenic Mitigation Options (RAAMO) tests 42 rainwater harvesting systems.  While less than half were contaminated by coliform bacteria in the monsoon period, this increased markedly during the dry season.    Again,  measurement and regular disinfection seems essential.                                      

Pond Sand Filters 

 

    It seems logical to collect river water in a pond, and then filter it naturally.  Again this has been done for centries.  Then it can be filtered as it goes into a second pond by sand or soil.  A pond sand filter can purify water for several hundred people so that the overall cost (per person)  is about the same as a deep tube well, but it probably needs more careful maintenance.    The webmaster photographed one system in 2004.   At first it was not bacteria free but it was improved and is bacteria free now.   The Phase 2 report of May 2005 by the Arsenic Policy Support Unit (APSU) "Risk Assessment of Arsenic Mitigation Options (RAAMO) tests 42 Pond Sand Filter systems and found that 95% had bacteria both in the monsoon and in the dry seasons.  They attribute this to inadequate maintenance and poor filter depth.  Again no indication was given that disinfectant (lime) was used as recommended by DCH in all their projects.  

The abstract of a comparative field study on the effectiveness of arsenic removal from groundwater by household sand filters is available on the ACS website.  

In India,  
the Jal-TARA Slow Sand Filter is a common water purification systems comprise of chlorination, coagulation and sand filtration techniques. Of all these techniques, sand filtration offers a chemical- free, reliable and economical treatment. Jal-TARA Slow Sand Filter is designed to treat drinking water using slow sand filtration technique as per the specifications of World Health Organisation (WHO). Jal-TARA filter is a biological filter merged with advanced technique of fabric protection to improve and simplify the traditional process of slow sand filtration. Two type of filtration act together to improve the quality of water: It consists of a gravel filter to remove turbidity, and sand bed filters to completely remove pathogenic bacteria from raw water.     
Large Scale Arsenic Removal Systems

    There are several  arsenic removal methods, which are appropriate for a large scale (small town) or a medium (village) scale. They are particularly appropriate for countries which have developed a central water supply and can therefore use the economy of scale.   Those must be tested in the field , and attempts must be made to manufacture equipment locally to make them affordable. The web masters have not done so and merely list them below. 
A list of larger scale technologies.

    In Bangladesh, UNICEF have helped the Department of Public Health Engineering (DPHE), Government of Bangladesh, to install over 40 community-based arsenic removal plants in different parts of Bangladesh, and  they are running well with the active participation of the community.   Each plant can produce approximately 3,600 liters of filtered water every 15 hours. The arsenic contained in the treated water is below 0.01 mg/L,  which is below the WHO and the new EPA guidelines.   The communities each employ one caretaker for each plant. They are paying salary to the caretaker, the electric bill, incidental expenses, and generating funds to purchase the chemicals in the future.    This experience is very promising for communitoes of 10,000 people or more where people are willing to walk to the central purification system to collect their water.  Again the webmasters have no up to date report of the success of these purification methods.

The long term future

    In 1998 there was a confusing controversy by some over enthusiastic people  (e.g. see the article by Bridge and Husain
) that  the problem is a barrage on the Ganges river.   However this seems to be reliably repudiated (by Dr McArthur from UCL among others).    TIn the longer term (50 year time scale) a national water policy was promulgated  in 2004 to replace the previous one which produced the arsenic problem.   It emphasized use of surface waters.   Yet many more people are turning deep tube wells than surface waters.    Many hyrdrologists see no problem with this.  The long term, will presumably use water piped from a central system of some sort, and the village size piped systems being pioneered by DCH seem to be a step in this direction.T.

Improving the Diet

    An important issue for coping with arsenic exposure  is the effect of diet.  A general issue can be stated:  there  is frequently more than one cause of a cancer or a lesion.  For example lung cancer can be caused by cigarette smoking or asbestos or both together,  in  a synergistic  way such that the risks multiply (rather than add) when  both  are present.   In the USA it has been found that people who  have  a good diet of fresh fruitand vegetables  (5 servings per day) have half  the risk of many cancers, including  lung cancers   caused by cigarettes,  as  those without a good diet.  By  analogy,  one might expect that the  lung  cancer risk from arsenic will be less among those with a good diet,  but this is not yet supported by direct data.  Indeed, there are  anecdotal  indications from Bangladesh that a good diet reduces  skin lesions also.  Clearly,  it is a good approach  for many reasons,  but epidemiological studies  to confirm this are highly desirable.
   

    There are several specific chemicals that have been suggested that would either (i) help to prevent arsenic lesions by rapid removal of arsenic from the body or (ii) help to cure arsenic lesions.  Encouragement of methylation of the arsenic probably accelerates methylation, but the methylation has been suggested as a cause of internal cancers.  
The specific chemical that has come to the mind of many health experts is selenium.   It was noted in the 1930s that effects of excess selenium can be counteracted by adding arsenic to the diet because As and Se combine.   Does the inverse take place?  It  is  reported that areas with high incidence of arsenical lesions have  low selenium  in the water.  Some victims have low selenium levels.   Does adding selenium to the diet really help, either to prevent the lesions from forming (likely), or to treat them afterwards (less likely)? We have,  with help from others, compiled a list of references and a recent paper  on the subject.    Professor Zuberi of Rajshashi University has suggested methionine to reduce the arsenic lesions.  Dr OGB Nambiar has suggested that ferrous sulphate, after conversion to sulfide by bacteria in the colon, absorbs arsenic and assists safe excretion.   The evidence for these remains indirect, and there may be (as suggested above) competing adverse effects.  Only good epidemiology can tell.

UNU/BUET meeting

Discussion of technologies in May 2001,
primarily in the context of Bangladesh,  in the following talks which can be downloaded:

Title
Contents



top of page

Reviews

Partial List of Projects both Govt. and non-Govt from M.L.R.Chowdhuri's book

Two reports on 4 small scale systems (
READ-F, SONO 45-25, Sidko and MAGC/ALCAN). are available: one from GMU  and a  poster from OCETA .


Early reviews of Arsenic Removal Technologies by Susan Murcott of MIT:
1999 paper, 2000 abstract

Review of arsenic removal by U.S. EPA

Early Finnish Comparison of various test methods
Finnish review of arsenic removal from groundwater

Small Systems

Javed Iqbal, Ho-Jeong Kim, Jung-Seok Yang, Kitae Baek, and  Ji-Won Yang. Removal of arsenic from groundwater by micellar-enhanced ultrafiltration (MEUF).Chemosphere, July 31, 2006.

Central Electrochemical Research Institute (CECRI), Karaikudi, India with the sponsorship of Department of Science and Technology (DST),New Delhi, India has developed a Domestic 2A capacity Electro Arsenic Purifier for Drinking Water, which can treat 2L of drinking water per one hour. This unit will reduce the arsenic level from 3ppm to 20ppb (WHO standard). This can also be operated with the use of Solar Energy. The Novelty of the Arsenic Purifier is this will removal both

arsenite and atsenate with high effieiency (reduce to 10ppb level). CECRI also developed a Community model Electro Arsenic Purifier for Drinking water, which can treat 40L of drinking water per one hour.The cost of the one 2A Arsenic Purifier is Rs.6,000. The cost of treatment of water is 3paise.Those who are all interested may contact:
Dr.S.VASUDEVAN
Electroinorganic Chemicals Division
Central Electrochemical Research Institute
Karaikudi – 630 006
Phone: 91 4565 227550 – 227559; Fax: 91 4565 227779Mobile: 9442552441
Email: svdevan_2000 @ yahoo.com, vasudevan65 @ gmail.com



SONO Filter, a modification of the 3 jar Kalshi filter, developed by Dr Hussam in USA and extensively used in Bangladesh particularly near Kushtia.  As noted above it has been approved by the Government of Bangladesh.   It costs approximately $30. 

Contact:   Dr. A.K.M.Munir,  COURT PARA,   KUSHTIA, BANGLADESH.
        Tel:071-61335,61909           Mob:0171-275041             Fax:088-071-61235
        e-mail:akmmunir2003@yahoo.com
We link here to several pdf files about using the filter.
Paper by Khan et al. abut the filter

 As filtration pictures.pdf
SONO FILTER IN USE_11.pdf
 Sono Filtering 4000 ppb As.pdf
Comment on OCETA poster

MAGC/ALCAN We have limited information about this system.  However it has been approved by the Government of Bangladesh,    Mr M. Saber Afzal claims that it is the cheapest system with acost of Taka 1,950 ($32,50)  which includes everything.

Paul Friot, of Friot Corporation, Ayer, MA, USA http://www.friot.com has US patent 6,368,510 B2 for a "Method and Apparatus for the Removal of Arsenic from Water" using a two stage process:  manganese greensand oxidizer to convert arsenite to arsenate,  followed by an anion exchange resin. 

Arup K. SenGupta, of Lehigh University has developed and collegaues at Bengal Engineering College in Howrah, West Bengal, have installed alumina filter systems for $1250 for 300 housholds or $1 per person  Their detailed paper of the results of followup on over 150 medium sized systems seems convincing.     

Dr Ashok Gadgil from Lawrence Berkeley Labs is developing a filter with coal ash

Susan Murcott at MIT has developed a sand filter called the KANSHAN filter

Australians are develpong a solar energy operated
distillation unit which will remove arsenic and many other pollutants.

Calgon Carbon introduces As removal systems

Silver Ceramic Water purifiers as used in Nepal:  (Nepal file)  (local file)


Recommendations for water supply in arsenic mitigation: a case study from Bangladesh. B. Hoque, AA Mahmood, M. Quamruzzaman et al. Public Health (2000), 114, 488-494


A Simple Household Device to Remove Arsenic from Groundwater and Two Years Performance Report of Arsenic Removal Plant for Treating Ground Water  with Community Participation.
  School of Environmental Studies, Jadavpur University, Calcutta-700032, India

Ferric Oxydioxide and Settling by Dr. Richard Anstiss of New Zealand and Professor Mustaque Ahmed (being tested in Bangladesh) procedure presented by Dr. Anstiss at Remediation Conference at DCH, Dhaka, Dec. 14 1998


RedoxTreatment of Groundwater to Remove Arsenic by Biorem International, Inc.


Removal of arsenic from drinking water with enhanced hybrid aluminas and composite metal oxide particles by B. Kepner, J. Spots, E. Mintz,J. Cortopassi, P. Abrahams, C. Gray, S. Mathur


A Permeable Grog for a Low Cost Water Purifier


A review of the SOS procedures for helping the villagers


BUT  be warned by the 6th report from Jadavapur University

Larger systems

ADI have another large scale removal device:   "ADI's MEDIA G2"


Membrane distillation


A Swedish Group with a new water purification technology called membrane distillation. It is able to remove all arsenic 3 and 5 completely. It has been tested at Sandia National Laboratory,  Texas University in El Paso, and in Sweden. It costs roughly what all advanced systems cost but has three advantages:
    1    Removes arsenic completely,
    2    Requires very little maintenance or component replacement,
    3    If waste heat is available, the cost of the water is very low indeed
So far we only have a description in Swedish .


SORB 33 Arsenic Removal Systems , by Severn Trent Services.


At the 5th International Arsenic Conference in San Diego, the purification systems successfully used in Vietnam (particularly in Hanoi) were described.


Apyron Technologies, formerly as Project Earth Industries, Joint Venture partners with RPM, Marketing Pvt. Ltd.
Press release 1 Press release 2


Pure Safe Water Solutions
have extensive experience in water purification systems for populations of 1,000 to 10,000 people. They have added the Apyron system to enable them to remove arsenic.


August  2000 Lecture by Matt Simmons on his remediation option.

Matt Simmons' page , with a copy of the patent and the report done on mine water.


Arsenic Remediation Technology (AsRT) Environmental Research Institute (Nikos Nikolaidis, Jeffery Lackovic, Gregory Dobbs, and Larry M. Deschaine). In situ and ex situ remediation and treatment technique for soil/sediment and water. For a good description see the article 18 Mar 98: "Filter cleans arsenic tainted water ," at Environmental News Network website. (tested in the USA)


Department of Chemistry, New Mexico State University
Remediation Of Arsenic Using Ferrate

Division of Land and Water Resources Spodic material for in situ treatment of arsenic in ground water


SUBRA , Copper, Chromium And Arsenic removal from tannery and timber treatment effluents

Arsenic Solutions Inc. combine skills from many groups


Water Treatment Methods by Martin Wegelin, Abdul Motaleb et al
.


SODIS - an arsenic mitigation option?


SORAS - a simple arsenic removal process


Harbauer Environmental Technology
by Harbauer GmbH & Co KG


Enviro-Main Filter Inc.

HVR arsenic project -development of manufacturing capability in India to produce arsenic removal equipment.


Barry Rosen's web site

"Oxidation/direct filtration technology for arsenic, manganese, and iron in ground water" - Industry Canada Environment Affairs Branch and ADIInc.

Australian CSIRO remediation methods

"Australian science tames arsenic pollution" -

Media release, Australian Nuclear Science and Technology Organization (ANSTO)


Info & products related to solar distillation.


"Solar Water disinfection Technologies"

"Lo-tech patented arsenic removal system" Solar Purification Company Inc.


Arsenic Removal by Enhanced Coagulation and Membrane Processes (paper from Janet Hering)


Use of chitostan derived from clam shells


HYDRO-Solutions and Purification This arsenic removal system was designed to remove arsenic from Alaskan mining wastes. It is claimed by its' proponents to be the most inexpensive (both capital & recurrent costs) process for commercial, industrial, and municipal arsenic removal. They also have a selenium removal methodology."


Purification technology by Krudico


Countertop  Water Distiller

Osmosis System for removal of arsenic


Biological process for removal

Metals and Arsenic Removals Inc (MARTI)

Pollard Industries have a system involving reverse osmosis and filtration to bring mine waters with 500 ppb of arsenic down to 1 ppb.




Please provide any other useful information to wilson5@fas.harvard.edu

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